Novel Engineered Nanocrystals for Nonvolatile Memory

 

Researchers: Jianlin Liu, Ruigang Li, Dengtao Zhao, Yan Zhu, Bei Li, Huimei Zhou, Jingjian Ren, Mario Olmedo

Collaborators: Roger Lake (UCR), Yi Shi (Nanjing University), Jane Chang (UCLA), Feng Liu (U. Utah), Chongwu Zhou (USC), Jeanie Lau (UCR), Jory Yarmoff (UCR), Jian-Guo Zheng (UCI)

 

Motivation of Research: To search future nonvolatile memory technologies, many recognize that nanocrystal memory shall be a straightforward solution to state-of-the-art flash memory, which will soon run into trouble. Though Si nanocrystals as floating gate already outperform continuous floating gate for this application, assembly of other novel nanocrystals may keep the journey going into future.  

 

Available Publications:

Incomplete Overview: We proposed and demonstrated the use of various silicide-based nanocrystals as floating gate for memory applications. Our effort in this field also includes the demonstration of Ge/Si heteronanocrystal (or core-shell nanocrystal) memories. In the mean time, we also used simple numerical simulations to understand the new device operation principles. We are currently working to further engineer new nanocrystals and their ordered arrays for memory applications. Please refer to the following publications:

 

J156. “Non-volatile memory effect of a high-density NiSi nano-dots floating gate memory using a single triangular-shaped Si nanowire channel”

         Jingjian Ren, Dong Yan, Sheng Chu, and Jianlin Liu

         Appl. Phys. A 111, 719(2013) view pdf

 

J149. “Rapid thermal oxygen annealing formation of nickel silicide nanocrystals for nonvolatile memory”

          H. M. Zhou, Z. L. Li, J. –G. Zheng, and J. L. Liu

          Appl. Phys. A 109, 535(2012) view pdf

 

J147. “Nonplanar NiSi Nanocrystal Floating-Gate Memory Based on a Triangular-Shaped Si Nanowire Array for Extending Nanocrystal Memory Scaling Limit”

         Jingjian Ren, Bei Li, Jian-Guo Zheng, Mario Olmedo, Huimei Zhou, Yi Shi, and Jianlin Liu

         IEEE Electron Device Letters 33, 1390(2012) view pdf

 

J146. “Strain-less directed self-assembly of Si nanocrystals on patterned SiO2 substrate”

          Jingjian Ren, Hao Hu, Feng Liu, Sheng Chu, and Jianlin Liu

          J. Appl. Phys. 112, 054311 (2012) view pdf

 

J141. “Temperature-Dependent Electron Transport in Highly Ordered Co/Al2O3 Core-Shell Nanocrystal

          Memory Synthesized with Di-Block Co-Polymers”

          Huimei Zhou, James A. Dorman, Ya-Chuan Perng, Jane P. Chang, and Jianlin Liu

          J. Appl. Phys. 111, 064505(2012) view pdf

 

J139. “High-density NiSi nanocrystals embedded in Al2O3/SiO2 double-barrier for robust retention of nonvolatile memory”

          Jingjian Ren, Bei Li, Jian-Guo Zheng, and Jianlin Liu

          Solid-State Electronics 67, 23(2012) view pdf

 

J137. “Carbon nanotube memory by the self-assembly of silicon nanocrystals as charge storage nodes”

          Mario Olmedo, Chuan Wang, Koungmin Ryu, Huimei Zhou, Jingjian Ren, Ning Zhan, Chongwu Zhou, and Jianlin Liu         

          ACS Nano 5, 7972(2011) view pdf

 

J134. “Vapor-solid-solid growth of NiSi2 nanocrystals for memory applications”

          Bei Li, Jianlin Liu, Reuben D. Gann, Jory A. Yarmoff, and Yu Zhu

          IEEE Transactions on Nanotechnology 10, 1120(2011) view pdf

 

J128.  “TiSi2 nanocrystal metal oxide semiconductor field effect transistor memory”

          Huimei Zhou, Bei Li, Zheng Yang, Ning Zhan, Dong Yan, Roger K. Lake, and Jianlin Liu

          IEEE Transactions on Nanotechnology 10, 499(2011) view pdf

 

J127. “Memory characteristics of ordered Co/Al2O3 core-shell nanocrystal arrays assembled by di-block co-polymer process”

         Huimei Zhou, James A. Dorman, Ya-Chuan Perng, Stephanie Gachot, Jian-Guo Zheng, Jane P. Chang, and Jianlin Liu

         Appl. Phys. Lett. 98, 192107(2011) view pdf

 

J125. “Nonvolatile memories with Ge/Si heteronanocrystals as floating gate”

          Bei Li, and Jianlin Liu

          IEEE Transactions on Nanotechnology 10, 284(2011) view pdf

 

J118. “Synthesis of high-density PtSi nanocrystals for memory applications”

          Bei Li, Jingjian Ren and Jianlin Liu

          Appl. Phys. Lett. 96, 172104(2010)

 

C57. “Study of the effects of growth temperature and time on the alignment of Si quantum dots on hafnium oxide coated single wall carbon nanotubes”

        Mario Olmedo, Alfredo A. Martinez-Morales, Gang Liu, Emre Yengel, Cengiz S. Ozkan, Chun Ning Lau,

        Mihrimah Ozkan, and Jianlin Liu

        ICSI-6, May 17-22, 2009, Los Angeles

        Thin Solid Films 518, S35(2010)

 

C56. Self-assembled Ge/Si hetero-nanocrystals for nonvolatile memory application”

       Bei Li, and Jianlin Liu

       ICSI-6, May 17-22, 2009, Los Angeles

      Thin Solid Films 518, S262(2010)

 

C55. Performance enhancement of TiSi2 coated Si nanocrystal memory device

       Huimei Zhou, Reuben Gann, Bei Li, Jianlin Liu and J. A. Yarmoff

      MRS Spring 2009, San Francisco, USA, Mater. Res. Soc. Symp. Proc. Vol. 1160, 1160-H01-05, 2009

 

C54. “VSS-induced NiSi2 nanocrystal memory”

       Bei Li, and Jianlin Liu

       MRS Spring 2009, San Francisco, USA, Mater. Res. Soc. Symp. Proc. Vol. 1160, 1160-H01-09, 2009

 

J112. “CoSi2-coated Si nanocrystal memories”

          Bei Li, and Jianlin Liu

          J. Appl. Phys. 105, 084905(2009)

 

J111. “Periodic alignment of Si quantum dots on hafnium oxide coated single wall carbon nanotubes”

         Mario Olmedo, Alfredo A. Martinez-Morales, Gang Liu, Emre Yengel, Cengiz S. Ozkan,

         Chun Ning Lau, Mihrimah Ozkan, and Jianlin Liu

         Appl. Phys. Lett. 94, 123109(2009)

 

C53.  “High-performance hetero-nanocrystal memories”

        Bei Li, Yan Zhu, Huimei Zhou, and Jianlin Liu

        2008 9th International Conference on Solid-state and Integrated Circuits Technology, Oct 20-Oct 23, 2008, Beijing, (Invited)

 

J104. “A TiSi2/Si hetero-nanocrystal memory operated with hot carrier injections”

          Y. Zhu, and J. L. Liu

          IEEE Transactions on Nanotechnology 7, 305(2008)

 

C51. “Self-aligned TiSi2/Si Hetero-nanocrystal Nonvolatile Memory”

        Yan Zhu, Bei Li and Jianlin Liu

        MRS Spring 2007, San Francisco, USA, Mater. Res. Soc. Symp. Proc. Vol. 997, 0997-I02-05, 2007

 

J97. “Ge/Si heteronanocrystal floating gate memory”

       Bei Li, Jianlin Liu, G. F. Liu, and J. A. Yormoff

       Appl. Phys. Lett. 91, 132107(2007)

 

J91. “Fabrication and characterization of TiSi2/Si heteronanocrystal metal-oxide-semiconductor memories”

       Y. Zhu, B. Li, and J. L. Liu

       J. Appl. Phys. 101, 063702(2007)

 

J89. “Numerical investigation of transient capacitance of Ge/Si hetero-nanocrystal memory in retention mode”

        Yan Zhu, Dengtao Zhao, and Jianlin Liu

         Journal of Applied Physics 101, 034508(2007)

 

J88. TiSi2/Si heteronanocrystal metal-oxide-semiconductor-field-effect-transistor memory”

        Yan Zhu, Bei Li, Jianlin Liu, G. F. Liu and J. A. Yarmoff

        Applied Physics Letters 89, 233113(2006)

 

J83. “Emerging memory devices: Nontraditional possibilities based on nanomaterials and nanostructures”

        K. Galatsis, Y.Y. Botros, K. Wang, Y. Yang, Y. H. Xie, F. Stoddart, R. Kaner, C. Ozkan, J. L. Liu,

        M.Ozkan, C. Zhou, and K. W. Kim

        IEEE Circuits & Devices Magazine, 22, 12(2006)

 

J80. “Transient process in a Ge/Si hetero-nanocrystal p-channel memory”

        Dengtao Zhao, Yan Zhu, Ruigang Li, and Jianlin Liu

        Solid-state Electronics 50, 362(2006)

 

J77.  “Self-aligned TiSi2/Si heteronanocrystal nonvolatile memory”

         Yan Zhu, Dengtao Zhao, Ruigang Li, and Jianlin Liu

          Appl. Phys. Lett. 88, 103507(2006)

 

J75. “Charge storage in a metal-oxide-semiconductor capacitor containing cobalt nanocrystals”

        Dengtao Zhao, Yan Zhu, and Jianlin Liu

        Solid-State Electronics 50, 268(2006)

 

J72. “Simulation of a Ge-Si Hetero-Nanocrystal Memory”

        D. T. Zhao, Y. Zhu, R. G. Li, and J. L. Liu

        IEEE Trans. on Nanotechnology, 5, 37(2006)

 

J69. “Simulation of a cobalt silicide/Si hetero-nanocrystal memory”

        Dengtao Zhao, Yan Zhu, Ruigang Li, and Jianlin Liu

        Solid-State Electronics 49, 1974(2005)

 

J65. “Threshold voltage shift of heteronanocrystal floating gate flash memory”

        Yan Zhu, Dengtao Zhao, Ruigang Li, and Jianlin Liu

        J. Appl. Phys. 97, 034309(2005)

 

C46.  “Threshold Voltage Shift in Hetero-Nanocrystal Floating Gate Flash Memories

        Yan Zhu, Dengtao Zhao, Ruigang Li, and Jianlin Liu

        MRS Fall 2004, Boston, USA, November 29-December 3, 2004

 

C45.  “Computer Simulation of Charging/Erasing Transients of a Ge/Si Hetero-nanocrystal-based Flash Memory”

        Dengtao Zhao, Yan Zhu, Ruigang Li, and Jianlin Liu

        MRS Fall 2004, Boston, USA, November 29-December 3, 2004